Balancing ion conductivity, mechanical strength, and alkali stability is a significant challenge in the application of anion exchange membranes (AEMs) in anion exchange membrane fuel cells (AEMFCs). In this study, rigid poly (4-vinylbiphenyl chloride) (PVB) and flexible polystyrene-b-poly(ethylene-co-butylene)-b-polystyrene (SEBS) are selected as the polymer backbones to create semi-interpenetrating network (SIPN) AEMs. To achieve high ionic conductivity, quaternary ammonium groups are grafted onto each PVB structural unit, and TMHDA reacts with CMSEBS to construct a cross-linking network whil...