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A novel approximation to the relation between reduced molecular potential of C1-3 hydrocarbon gases and their compressibility factor

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成果类型:
期刊论文
作者:
Yang, Xiaohong*;Zhang, Shunxi;Zhu, Weiling
通讯作者:
Yang, Xiaohong
作者机构:
[Zhang, Shunxi; Yang, Xiaohong; Zhu, Weiling] Wuhan Polytech Univ, Dept Chem & Environm Engn, Wuhan 430023, Peoples R China.
通讯机构:
[Yang, Xiaohong] W
Wuhan Polytech Univ, Dept Chem & Environm Engn, Wuhan 430023, Peoples R China.
语种:
英文
关键词:
Compressibility factor;hydrocarbon gas;molecular potential;intermolecular interaction;distribution function;temperature
期刊:
Petroleum Science and Technology
ISSN:
1091-6466
年:
2016
卷:
34
期:
21
页码:
1755-1760
机构署名:
本校为第一且通讯机构
院系归属:
化学与环境工程学院
摘要:
Based on symmetric intermolecular interactions approximation, a novel relation between compressibility (Z) factor of hydrocarbon gases and molecular potential has been developed. The relation indicated that the Z factor was an exponential function of the depth of potential well, which was derived to be proportional to the molecular potential. By this relation, the reduced molecular potentials of methane, ethane, and propane were determined at the same temperature. The obtained reduced potentials appeared the standard L-J curve shape, suggesting the rationality and success of this approximation...

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