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Determination of Tl(III) and Tl(I) in food samples with two-step direct immersion single-drop microextraction followed by graphite furnace atomic absorption spectrometry

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成果类型:
期刊论文
作者:
Chen, Shizhong;Yan, Juntao;Wang, Chunlei;Zhang, Chenghao;Lu, Dengbo
通讯作者:
Shizhong Chen
作者机构:
[Chen, Shizhong; Lu, Dengbo] Wuhan Polytech Univ, Coll Food Sci & Engn, Wuhan 430023, Peoples R China.
[Wang, Chunlei; Yan, Juntao; Zhang, Chenghao] Wuhan Polytech Univ, Coll Chem & Environm Engn, Wuhan 430023, Peoples R China.
通讯机构:
[Shizhong Chen] C
College of Food Science and Engineering, Wuhan Polytechnic University, Wuhan 430023, China
语种:
英文
关键词:
Two-step direct immersion single-drop micro-extraction;Graphite furnace atomic absorption;spectrometry;Thallium speciation;Food composition
期刊:
Journal of Food Composition and Analysis
ISSN:
0889-1575
年:
2023
卷:
117
页码:
104967
基金类别:
CRediT authorship contribution statement Shizhong Chen: Investigation, Supervision, Methodology, Conceptualization, Writing – original draft, Writing – review & editing. Juntao Yan: acquisition, Validation, Methodology, Investigation, Formal analysis. Chunlei Wang: acquisition, Investigation, Formal analysis and Methodology. Chenghao Zhang: Methodology. Dengbo Lu: Data curation, Software and Visualization.
机构署名:
本校为第一机构
院系归属:
食品科学与工程学院
化学与环境工程学院
摘要:
In this study, a new procedure of two-step direct immersion single-drop microextraction (TS-DI-SDME) was firstly developed for the sequential separation and enrichment of Tl(III) and Tl(I) before graphite furnace atomic absorption spectrometry detection. At pH 6.0, Tl(III) selectively reacts with 1-(2-Pyridylazo)− 2-naphthol to form the complexes which can be extracted into one organic drop, while Tl(I) remained in the solution. Then, another organic drop containing dicyclohexano-18-crown-6 was immersed in the sample solution after the extract...

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