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Synthesis and properties of methyl palmitate-polyurea phase change microcapsules

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成果类型:
期刊论文
作者:
Chen, Liuwei;Lao, Jiayue;Ma, Jintao;He, Zerui;Fu, Wanwan;...
通讯作者:
Fu, WW;Luo, YS
作者机构:
[Peng, Hao; Fu, Wanwan; Liu, Jiesheng; Chen, Liuwei; Lao, Jiayue; Ma, Jintao; Fu, WW; He, Zerui; Fang, Tao] Wuhan Polytech Univ, Sch Civil Engn & Architecture, Wuhan 430023, Peoples R China.
[Luo, Yanshu; Luo, YS] Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou 325035, Peoples R China.
通讯机构:
[Luo, YS ; Fu, WW ] W
Wuhan Polytech Univ, Sch Civil Engn & Architecture, Wuhan 430023, Peoples R China.
Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou 325035, Peoples R China.
语种:
英文
关键词:
Phase change microcapsules;Methyl palmitate;Polyurea;Thermal energy storage;Interfacial polymerization
期刊:
Polymer
ISSN:
0032-3861
年:
2025
卷:
319
页码:
128073
基金类别:
National Natural Science Foundation of China [22308263]; Natural Science Foundation of Wuhan [2024040801020333]
机构署名:
本校为第一且通讯机构
院系归属:
土木工程与建筑学院
摘要:
In this study, a methyl palmitate-polyurea phase change microcapsule (MPCM) was successfully synthesized by interfacial polymerization with methyl palmitate with high latent heat as the core material and tolylene-2,4-diisocyanate (TDI) and diethylene triamine (DETA) as the shell monomers. The effects of emulsifier type and content, cosolvent, reaction rate and core-shell mass ratio on the phase change properties of microcapsules were systematically discussed, and the optimum process was determined. A series of characterization techniques were u...

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