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Calcium single atoms stabilized by nitrogen coordination in metal–organic frameworks as efficient solid base catalysts

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成果类型:
期刊论文
作者:
Peng, Song-Song;Liu, Sai;Shao, Xiang-Bin;Zhang, Kai;Liu, Yang;...
通讯作者:
Sun, LB;Yan, JT
作者机构:
[Wang, Yang; Peng, Song-Song; Tan, Peng; Liu, Sai; Shao, Xiang-Bin; Sun, Lin-Bing; Liu, Yang; Zhang, Kai] Nanjing Tech Univ, Coll Chem Engn, Jiangsu Natl Synerget Innovat Ctr Adv Mat SICAM, State Key Lab Mat Oriented Chem Engn, 30 South Puzhu Rd, Nanjing 211816, Peoples R China.
[Yan, Juntao] Wuhan Polytech Univ, Coll Chem & Environm Engn, Wuhan 430023, Peoples R China.
通讯机构:
[Sun, LB ] N
[Yan, JT ] W
Nanjing Tech Univ, Coll Chem Engn, Jiangsu Natl Synerget Innovat Ctr Adv Mat SICAM, State Key Lab Mat Oriented Chem Engn, 30 South Puzhu Rd, Nanjing 211816, Peoples R China.
Wuhan Polytech Univ, Coll Chem & Environm Engn, Wuhan 430023, Peoples R China.
语种:
英文
关键词:
Basic sites;Ca single atoms;Metal-organic frameworks;Single-atom solid base catalysts
期刊:
Journal of Colloid and Interface Science
ISSN:
0021-9797
年:
2025
卷:
678
期:
Pt B
页码:
88-94
基金类别:
Acknowledgements This work was supported by the National Science Fund for Distinguished Young Scholars (22125804), the National Natural Science Foundation of China (22078155 and 22178163), and the Jiangsu Program for Excellent Postdoctoral Talent. We thank the photoemission end stations beamline 4B7A station in the Beijing Synchrotron Radiation Facility (BSRF) for help with the characterizations.
机构署名:
本校为通讯机构
院系归属:
化学与环境工程学院
摘要:
Considerable attention has been paid to the preparation of single-atom solid base catalysts (SASBCs) owing to their high activity and maximized utilization of basic sites. At present, the reported fabrication methods of SASBCs, such as two-step reduction strategy and sublimation capture strategy, require high temperature. Such a high activation temperature is easy to cause the sublimation loss of alkali or alkaline earth metal atoms and destructive to the support structure. Herein, a new SASBC, Ca(1)/UiO-67-BPY, is fabricated, in which the alkaline earth metal Ca sites are immobilized onto N-r...

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