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A novel separation and preconcentration methodology based on direct immersion dual-drop microextraction for speciation of inorganic chromium in environmental water samples

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成果类型:
期刊论文
作者:
Yan, Juntao;Zhang, Chenghao;Wang, Chunlei;Lu, Dengbo;Chen, Shizhong*
通讯作者:
Chen, Shizhong
作者机构:
[Wang, Chunlei; Yan, Juntao; Zhang, Chenghao] Wuhan Polytech Univ, Coll Chem & Environm Engn, Wuhan 430023, Peoples R China.
[Chen, Shizhong; Lu, Dengbo] Wuhan Polytech Univ, Coll Food Sci & Engn, Wuhan 430023, Peoples R China.
通讯机构:
[Chen, Shizhong] C
College of Food Science and Engineering, Wuhan Polytechnic University, Wuhan, 430023, PR China. Electronic address:
语种:
英文
关键词:
Direct immersion dual-drop microextraction;Graphite furnace atomic absorption spectrometry;Hexavalent chromium;Trivalent chromium;Water samples
期刊:
Talanta
ISSN:
0039-9140
年:
2023
卷:
255
页码:
123902
基金类别:
Author contributions Juntao Yan: acquisition, Validation, Investigation, Methodology, Formal analysis, Writing - original draft, Writing - review & editing. Chenghao Zhang: Investigation and Methodology. Chunlei Wang: acquisition, Investigation, Formal analysis and Methodology. Dengbo Lu: Data curation, Software and Visualization. Shizhong Chen: Investigation, Supervision, Methodology, Conceptualization, Writing - original draft, Writing - review & editing.
机构署名:
本校为第一机构
院系归属:
食品科学与工程学院
化学与环境工程学院
摘要:
In this study, for the first time, a novel separation and preconcentration method of direct immersion dual-drop microextraction (DIDDME) was proposed for the species of inorganic chromium (Cr(III) and Cr(VI)) followed by graphite furnace atomic absorption spectrometry detection. The methodology is based on that two organic drops hold on the needle tips of microsyringes were concurrently immersed in a stirred sample solution. Each drop contains a chelating reagent, which can react with a specific species under the same pH value. Therefore, Cr(III) and Cr(VI) can be selectively extracted into di...

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