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High capacitance LiMn2O4 microspheres with different microstructures as cathode material for aqueous asymmetric supercapacitors

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成果类型:
期刊论文
作者:
Xiao, Haowen;Wang, Yourong*;Xie, Kai;Cheng, Siqing*;Cheng, Xianzhong
通讯作者:
Wang, Yourong;Cheng, Siqing
作者机构:
[Cheng, Xianzhong; Xie, Kai; Wang, YR; Cheng, SQ; Wang, Yourong; Cheng, Siqing; Xiao, Haowen] Wuhan Polytech Univ, ICNEM, Sch Chem & Environm Engn, Wuhan 430023, Hubei, Peoples R China.
通讯机构:
[Wang, YR; Cheng, SQ] W
Wuhan Polytech Univ, ICNEM, Sch Chem & Environm Engn, Wuhan 430023, Hubei, Peoples R China.
语种:
英文
关键词:
Aqueous electrolyte;Asymmetric supercapacitor;Electrochemical performance;Hollow LiMn 2 O 4 microspheres;Porous LiMn 2 O 4 microspheres
期刊:
Journal of Alloys and Compounds
ISSN:
0925-8388
年:
2018
卷:
738
页码:
25-31
基金类别:
Hubei Province Excellent Science and Technology Innovation Team Project [T201407]
机构署名:
本校为第一且通讯机构
院系归属:
化学与环境工程学院
摘要:
Asymmetric supercapacitors (ASCS) with a battery-type electrode and a capacitor-type electrode have been regarded as the most promising energy-storage devices with high-energy and high-power densities. In this paper, the porous and hollow LiMn2O4 microspheres were prepared using MnCO3 microspheres as template and subsequently an ASCS with the as-prepared LiMn2O4 as cathode and activated carbon (AC) as anode in Li2SO4 aqueous electrolyte (designated by AC//LiMn2O4 ASCS) was assembled and investigated electrochemically. The results indicate that the porous LiMn2O4 exhibits a higher reversible ca...

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