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Enhanced Li+/Mg2+ selectivity of two-dimensional montmorillonite membranes by end-face and interfacial layer constraint for nanosheets

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成果类型:
期刊论文
作者:
Wen, Tong;Zhao, Yunliang;Kuang, Bowen;Sun, Yupeng;Li, Ying;...
通讯作者:
Zhao, YL;Zhang, TT
作者机构:
[Gao, Renbo; Wang, Huatao; Zhang, Lingjie; Li, Ying; Chen, Licai; Kuang, Bowen; Zhao, YL; Sun, Yupeng; Zhao, Yunliang; Wen, Tong] Wuhan Univ Technol, Sch Resources & Environm Engn, 34 Wenzhi St, Wuhan 430070, Hubei, Peoples R China.
[Zhao, YL; Zhao, Yunliang] Wuhan Univ Technol, State Key Lab Silicate Mat Architectures, 122 Luoshi Rd, Wuhan 430070, Hubei, Peoples R China.
[Zhao, YL; Zhao, Yunliang] Wuhan Clayene Technol Co Ltd, 36 Tangxunhu North Rd, Wuhan 430223, Hubei, Peoples R China.
[Zhang, Lingjie] Univ Autonoma San Luis Potosi, Fac Ciencias, Ave Parque Chapultepec 1570, San Luis Potosi 78210, Mexico.
[Zhang, Tingting] Wuhan Polytech Univ, Sch Chem & Environm Engn, 68 Xuefu South Rd, Wuhan 430023, Hubei, Peoples R China.
通讯机构:
[Zhao, YL ; Zhang, TT ] W
Wuhan Univ Technol, Sch Resources & Environm Engn, 34 Wenzhi St, Wuhan 430070, Hubei, Peoples R China.
Wuhan Univ Technol, State Key Lab Silicate Mat Architectures, 122 Luoshi Rd, Wuhan 430070, Hubei, Peoples R China.
Wuhan Clayene Technol Co Ltd, 36 Tangxunhu North Rd, Wuhan 430223, Hubei, Peoples R China.
Wuhan Polytech Univ, Sch Chem & Environm Engn, 68 Xuefu South Rd, Wuhan 430023, Hubei, Peoples R China.
语种:
英文
关键词:
Two-dimensional nanochannel membrane;Montmorillonite;Separation ofLi+andMg2+;Channel constraint
期刊:
Separation and Purification Technology
ISSN:
1383-5866
年:
2024
卷:
339
页码:
126707
基金类别:
National Key R & D Program of China [2022YFC2906300]; National Natural Science Foundation of China [52374275]; Natural Science Foundation of Hubei Province [2023AFA084]
机构署名:
本校为通讯机构
院系归属:
化学与环境工程学院
摘要:
The novel two-dimensional (2D) channel membranes have great potential for effective Li+/Mg2+ separation due to the rapid ion transport and precise adjustment of their channels. However, the solution composition greatly affects the control of channel height, resulting in an unsatisfactory selectivity performance. Herein, the 2D montmorillonite membranes are used to understand the causes of channel instability and explore the effective solutions. It is found that the changes in solution component can enlarge the channel height by changing the cross-linking constraint of Fe3+ between MMT nanoshee...

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