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Unveiling the role of Mn-Cd-S solid solution and MnS in MnxCd1-xS photocatalysts and decorating with CoP nanoplates for enhanced photocatalytic H2 evolution

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成果类型:
期刊论文
作者:
Xiong, Minghui;Qin, Yi;Chai, Bo*;Yan, Juntao;Fan, Guozhi;...
通讯作者:
Chai, Bo;Xu, Fang
作者机构:
[Qin, Yi; Wang, Chunlei; Song, Guangsen; Chai, Bo; Xu, Fang; Xiong, Minghui; Yan, Juntao; Fan, Guozhi] Wuhan Polytech Univ, Sch Chem & Environm Engn, Wuhan 430023, Peoples R China.
通讯机构:
[Chai, B; Xu, F] W
Wuhan Polytech Univ, Sch Chem & Environm Engn, Wuhan 430023, Peoples R China.
语种:
英文
关键词:
MCS-0.5;CoP nanoplates;Photocatalytic H-2 evolution;Charge separation
期刊:
Chemical Engineering Journal
ISSN:
1385-8947
年:
2022
卷:
428
页码:
131069
基金类别:
Key Research and Development Project of Hubei Province [2020BBB068]; Nature Science Foundation of Hubei ProvinceNatural Science Foundation of Hubei Province [2020CFB400, 2019CFB159]; Applied Basic Research Programs of Wuhan Science and Technology Bureau [2020020601012263]
机构署名:
本校为第一且通讯机构
院系归属:
化学与环境工程学院
摘要:
A series of MnxCd1-xS (0 < x < 1, marked as MCS-x) photocatalysts were synthesized by a facile hydrothermal method. The Mn-Cd-S solid solution and impurity phase of alpha-MnS would coexist in the as-prepared products once x >= 0.3. Among these photocatalysts, the MCS-0.5 sample exhibited the highest photocatalytic H-2 evolution rate of 5.540 mmol.g(-1).h(-1) with the lactic acid as sacrificial reagent, which may be due to the joint action of the formation of Mn-Cd-S solid solution promoting conduction band potential to enhance the reduction ability and Mn5 as the recombination center of photog...

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