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Determination of Antimony Speciation in Cow Milk Using Dispersive Micro-solid Phase Extraction Based on Fibrous TiO2@g-C(3)N(4)Nanocomposites and ICP-MS After Sample Pretreatment by Artificial Gastric Juice

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成果类型:
期刊论文
作者:
Chen, Shizhong*;Liu, Yuxiu;Wang, Chunlei;Yan, Juntao;Lu, Dengbo
通讯作者:
Chen, Shizhong
作者机构:
[Chen, Shizhong; Lu, Dengbo] Wuhan Polytech Univ, Coll Food Sci & Engn, Wuhan 430023, Peoples R China.
[Wang, Chunlei; Yan, Juntao; Liu, Yuxiu] Wuhan Polytech Univ, Coll Chem & Environm Engn, Wuhan 430023, Peoples R China.
通讯机构:
[Chen, Shizhong] W
Wuhan Polytech Univ, Coll Food Sci & Engn, Wuhan 430023, Peoples R China.
语种:
英文
关键词:
Antimony speciation;Artificial gastric juice;Cow milk;Dispersive micro-solid phase extraction;Fibrous TiO2@g-C3N4 nanocomposites;Inductively coupled plasma mass spectrometry
期刊:
Food Analytical Methods
ISSN:
1936-9751
年:
2020
卷:
13
期:
11
页码:
2102-2110
基金类别:
This work was financially supported by the Nature Science Foundation of Hubei Province (No. 2019CFB159) and the Research and Innovation Initiatives of Wuhan Polytechnic University (No. 2018J04 and 2018Y07).
机构署名:
本校为第一且通讯机构
院系归属:
食品科学与工程学院
化学与环境工程学院
摘要:
In this work, fibrous TiO2@g-C3N4 nanocomposites (FTGCNCs) were used as a new adsorbent of dispersive micro-solid phase extraction for speciation of antimony in cow milk, including Sb(III), Sb(V), residual, digestible, and total Sb. Samples were prepared with artificial gastric juice to achieve bioaccessible species of elements before ICP-MS determination. Besides, adsorption behaviors of Sb(III) and Sb(V) on FTGCNCs were investigated. The results showed that Sb(III) was quantitatively adsorbed on FTGCNCs in the pH range of 2.0–4.0, while Sb(V...

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