Decaglycerol monooleate (DGMO)-sodium caseinate (NaCas) complex was prepared by the self-assembly method. The particle size, polydispersity index (PDI), and zeta potential were used as indexes to investigate the effect of mass ratio of NaCas-to-DGMO on the complex. Furthermore, fluorescence spectroscopy, UV-Vis spectrophotometry, and Fourier transform infrared spectroscopy (FTIR) were used to characterize the NaCas-DGMO complex. The properties of the NaCas-DGMO complex, such as stability against pH and salts, and emulsifying property of soybean...