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Comparative reactivities of metal cation-catalyzed hydrolysis of p-nitrophenyl picolinate in micellar solutions

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成果类型:
期刊论文
作者:
Yu, XQ;Jiang, BY;Cheng, SQ;Huang, Z;Zeng, XC*
通讯作者:
Zeng, XC
作者机构:
[Zeng, XC] Sichuan Univ, Dept Chem, Chengdu 610064, Peoples R China.
Wuhan Polytech Univ, Dept Biol & Chem Engn, Wuhan, Peoples R China.
通讯机构:
[Zeng, XC] S
Sichuan Univ, Dept Chem, Chengdu 610064, Peoples R China.
语种:
英文
关键词:
catalysis;hydrolysis of PNPP;metal ion micelle
期刊:
Journal of Dispersion Science and Technology
ISSN:
0193-2691
年:
2003
卷:
24
期:
6
页码:
761-765
机构署名:
本校为其他机构
院系归属:
生命科学与技术学院
摘要:
Abstract Comparative reactivities of different metal ions in different micellar solutions (cationic, anionic, nonionic micelle) for the hydrolysis of p‐nitrophenyl picolinate (PNPP) were investigated spectrophotometrically at pH 7.0 and 25°C. The kinetics analysis was carried out by invoking a model of micellar catalysis. The results show that compared with metal ions in aqueous solution, cationic micelles inhibit metal ion catalyzed hydrolysis of PNPP, anionic micelles accelerate metal ion catalyzed hydrolysis of PNPP and nonionic micelles s...

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