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Immobilization of ionic liquids onto chloromethylated polystyrene as a strategy for highly efficient and selective recovery of Au(III) from gold slag and PCBs

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成果类型:
期刊论文
作者:
Zhang, Manman;Peng, Lifang;Li, Wenkang;Yan, Juntao;Wang, Chunlei;...
通讯作者:
Zhao, L
作者机构:
[Zhang, Manman; Wang, Chunlei; Sun, Ya; Yan, Juntao; Zheng, Mingming] Wuhan Polytech Univ, Sch Chem & Environm Engn, Wuhan 430040, Peoples R China.
[Li, Wenkang; Peng, Lifang; Zhao, Long] Huazhong Univ Sci & Technol, Sch Elect & Elect Engn, State Key Lab Adv Electromagnet Engn & Technol, Wuhan 430074, Peoples R China.
[Zheng, Mingming] Huzhou City Linghu Xinwang Chem CO LTD, Huzhou, Peoples R China.
[Zhao, Long; Zhao, L] Huazhong Univ Sci & Technol, Sch Elect & Elect Engn, Wuhan 430074, Peoples R China.
通讯机构:
[Zhao, L ] H
Huazhong Univ Sci & Technol, Sch Elect & Elect Engn, Wuhan 430074, Peoples R China.
语种:
英文
关键词:
Ionic liquids;Chloromethylated polystyrene beads;Au(III);Selectivity
期刊:
Separation and Purification Technology
ISSN:
1383-5866
年:
2024
卷:
337
页码:
126479
基金类别:
National Natural Science Foundation of China [22302153, 52102111]; Educational Commission of Hubei Province [B2022253]; Research and Innovation Initiatives of WHPU [2023Y25, 2023Y26]; South Taihu Elite Program
机构署名:
本校为第一机构
院系归属:
化学与环境工程学院
摘要:
The recovery of Au(III) has become a focal point of interest due to its significance in resource utilization and addressing environmental contamination. In this study, [C(3)NH(2)Mim]Cl-CMPS and PPh3-CMPS were successfully developed by immobilizing [C(3)NH(2)Mim]Cl and triphenylphosphine (PPh3) onto chloromethylated polystyrene beads (CMPS). The adsorbents demonstrated consistently high adsorption efficiency (>95 %) at a wide pH range. The [C(3)NH(2)Mim]Cl-CMPS and PPh3-CMPS exhibited exceptional selective adsorption ability for Au(III), and the adsorption process adhered to the PSO and Langmui...

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