The development of highly active and stable electrocatalysts for the hydrogen evolution reaction (HER) is central to the area of renewable energy. Si nanocomposites exhibited high efficiency in a light-induced hydrogen evolution reaction. However, there are few reports on the experimental application of the electrochemical HER. Herein, we report a simple synthesis of an intermetallic Pt2Si electrode using magnetron sputtering (MS) synthesis. The physical and electrochemical characterization of the materials was achieved by scanning electron microscopy (SEM), atomic force microscopy (AFM), X-ra...