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Magnetic optimization and regulation mechanism of La2CoMnO6 double-perovskite ceramics by Ti-doping at Mn-site

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成果类型:
期刊论文
作者:
Shi, Junwei;Shen, Qiang;Wang, Chuanbin;Hu, Mingzhe
通讯作者:
Hu, MZ
作者机构:
[Shi, Junwei] Wuhan Polytech Univ, Sch Chem & Environm Engn, Wuhan, Peoples R China.
[Hu, MZ; Hu, Mingzhe] Guizhou Minzu Univ, Coll Phys & Mechatron Engn, Guiyang 550025, Peoples R China.
[Shen, Qiang; Wang, Chuanbin] Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Peoples R China.
通讯机构:
[Hu, MZ ] G
Guizhou Minzu Univ, Coll Phys & Mechatron Engn, Guiyang 550025, Peoples R China.
语种:
英文
关键词:
La2CoMnO6;Double-perovskite;Ti-doping;Magnetic optimization;First-principle calculation
期刊:
Ceramics International
ISSN:
0272-8842
年:
2023
卷:
49
期:
12
页码:
20662-20671
基金类别:
National Natural Science Foundation of China [51972252, 51932006, 62261008]; National Science Foundation of Guizhou Province [ZK2021YB301]; Ministry of Education, China -111 Project [B13035]
机构署名:
本校为第一机构
院系归属:
化学与环境工程学院
摘要:
This work focuses on the magnetic optimization of La2CoMnO6 (LCMO) double-perovskite ceramics by Ti-doping at Mn-site. LCMO ceramics with different Ti-doping contents (LCMTxO, x = 0.1–0.4) were prepared by plasma activated sintering, and the effect of Ti-doping on the structural and magnetic properties of the ceramics is studied systematically. All the ceramics exhibit dense structure and small grain size, with a monoclinic P21/n crystalline structure. With the increasing of Ti-doping content, the proportions of Co2+ and Mn4+ in the LCMTxO cer...

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