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Study of ferroelectric nanodomains and the effect of grain size in BaTiO3 ceramics

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成果类型:
期刊论文
作者:
Fang, Chao*;Chen, Liangyan
通讯作者:
Fang, Chao
作者机构:
[Chen, Liangyan; Fang, Chao] Wuhan Polytech Univ, Dept Elect & Elect Engn, Wuhan 430023, Peoples R China.
通讯机构:
[Fang, Chao] W
Wuhan Polytech Univ, Dept Elect & Elect Engn, Wuhan 430023, Peoples R China.
语种:
英文
关键词:
BaTiO 3;ferroelectric domains;nanoceramics;phase transitions
期刊:
Philosophical Magazine Letters
ISSN:
0950-0839
年:
2012
卷:
92
期:
9
页码:
459-468
基金类别:
Department of Electronic Science and Technology, Huazhong University of Science and Technology, China [2009AA03Z445]; Department of Electrical and Electronic Engineering, Wuhan Polytechnic University, Wuhan, China
机构署名:
本校为第一且通讯机构
院系归属:
电气与电子工程学院
摘要:
Nanodomains and grain-size effects in BaTiO3 have been studied theoretically. In this article, we have calculated the long-range Coulomb interaction between ferroelectric nanodomains in a single BaTiO3 grain, and obtained information on the domain structure at various temperatures and grain sizes. The relation between transition temperature and the grain size is obtained by incorporating the domain-wall energy, the surface energy, and the stress energy into the Landau–Ginzburg free-energy density. The results show that 180° domains exist in f...

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