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Preparation of Li2MnO3 nanowires with structural defects as high rate and high capacity cathodes for lithium-ion batteries

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成果类型:
期刊论文
作者:
Sun, Ya;Guo, Minghui;Shu, Siwei;Ding, Deng;Wang, Chunlei;...
通讯作者:
Yan, JT;Zhang, YX
作者机构:
[Ding, Deng; Guo, Minghui; Wang, Chunlei; Sun, Ya; Shu, Siwei; Yan, Juntao] Wuhan Polytechn Univ, Coll Chem & Environm Engn, Wuhan 430023, Peoples R China.
[Zhang, Youxiang; Zhang, YX] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China.
通讯机构:
[Yan, JT ; Zhang, YX ] W
Wuhan Polytechn Univ, Coll Chem & Environm Engn, Wuhan 430023, Peoples R China.
Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China.
语种:
英文
关键词:
Cathode;Li-ion batteries;Li2MnO3;Nanowires;Structural defects
期刊:
Applied Surface Science
ISSN:
0169-4332
年:
2022
卷:
585
页码:
152605
基金类别:
National Sci-ence Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21271145, 52102111]; Key Research and Development Project of Hubei Province [2020BBB068]; Nature Science Foundation of Hubei ProvinceNatural Science Foundation of Hubei Province [2020CFB400]
机构署名:
本校为第一且通讯机构
院系归属:
化学与环境工程学院
摘要:
Li2MnO3, as a member of Li-rich and Mn-rich (LMR) layered oxides, has been considered as an appealing candidate for cathode preparation due to its high capacity and high voltage. Nevertheless, its commercialized application has been hindered by its demerits of poor ratability and capacity decay. Meanwhile, structural defects have been proven to influence the electrochemical activities of Li2MnO3. Herein, Li2MnO3 nanowires with varying numbers of structural defects were prepared and measured as cathode materials. rLMO-2 nws with the highest leve...

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