Highly efficient recovery of Re(VII) from uranium and molybdenum ores leaching solution by quaternary phosphonium modified cellulose microspheres

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成果类型：

期刊论文

作者：

Yu, Jiangtao;Zhang, Manman*;Wang, Nan;Zhai, Maolin;Hua, Rong;...

通讯作者：

Zhang, Manman;Que, Xueyan;Zhao, L

作者机构：

[Que, Xueyan; Yu, Jiangtao] Yangling Hesheng Irradiat Technol Co Ltd, Yangling 712000, Peoples R China.

[Zhang, Manman; Yan, Juntao; Li, Xiaofang] Wuhan Polytech Univ, Sch Chem & Environm Engn, Wuhan 430040, Peoples R China.

[Wang, Nan; Zhao, Long] Huazhong Univ Sci & Technol, Sch Elect & Elect Engn, State Key Lab Adv Electromagnet Engn & Technol, Wuhan 430074, Peoples R China.

[Zhai, Maolin] Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Radiochem & Radiat Chem Key Lab Fundamental Sci, Beijing 100871, Peoples R China.

[Hua, Rong] East China Univ Technol, State Key Lab Nucl Resources & Environm, Nanchang 330013, Jiangxi, Peoples R China.

通讯机构：

[Que, XY; Zhang, MM; Zhao, L ] H

Huazhong Univ Sci & Technol, Sch Elect & Elect Engn, Wuhan 430074, Peoples R China.

语种：

英文

关键词：

Cellulose microspheres;Quaternary phosphonium;Adsorption;U(VI)/Re (VII);Mo(VI)/Re(VII)

期刊：

Journal of the Taiwan Institute of Chemical Engineers

ISSN：

1876-1070

年：

2025

卷：

168

页码：

105937

DOI：

10.1016/j.jtice.2024.105937

基金类别：

Acknowledgements This work was supported by the Educational Commission of Hubei Province ( B2023050 ), Research of Wuhan Polytechnic University (NO. 2024RZ035 ), and the National Natural Science Foundation of China ( 22302153 and 52102111 ).

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本校为其他机构

院系归属：

化学与环境工程学院

摘要：

Background Efficient separation of Re from molybdenum and uranium ores holds significant implications for resource utilization and environmental conservation. Efficient separation of Re from molybdenum and uranium ores holds significant implications for resource utilization and environmental conservation. Methods A novel quaternary phosphonium (PPh 3 ) modified cellulose (CMS-g-VBPPh 3 NO 3 ) was synthesized through the halogenation reaction between PPh 3 and the VBC grafted cellulose intermediate (CMS-g-VBC). The recovery of Re was evaluated by batch and dynamic adsorption experiments. A nove...

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Highly efficient recovery of Re(VII) from uranium and molybdenum ores leaching solution by quaternary phosphonium modified cellulose microspheres

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