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Synthesis and property of unsymmetric bent-core liquid crystals based on 2,5-disubstitueted-1,3,4-oxadiazole

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成果类型:
期刊论文
作者:
Mao Zhipeng;You Hongjun;Wang Kun;Zhang Zhiyong*;Guan Jintao;...
通讯作者:
Zhang Zhiyong
作者机构:
[Mao Zhipeng; Dai Zhiqun; Wang Kun; You Hongjun; Zhang Zhiyong; Guan Jintao] Wuhan Polytech Univ, Dept Chem & Environm Engn, Wuhan 430023, Peoples R China.
[Xiang Ying] Guangdong Polytech Univ, Dept Technol, Inst & Informat Engn, Guangzhou 510006, Guangdong, Peoples R China.
通讯机构:
[Zhang Zhiyong] W
Wuhan Polytech Univ, Dept Chem & Environm Engn, Wuhan 430023, Peoples R China.
语种:
中文
关键词:
噁二唑;不对称弯曲形液晶;向列相;合成
关键词(英文):
Nematic phase;Oxadiazole;Synthesis;Unsymmetric bent-core liquid crystal
期刊:
有机化学
ISSN:
0253-2786
年:
2015
卷:
35
期:
12
页码:
2575-2582
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [11074054, 11374067]
机构署名:
本校为第一且通讯机构
院系归属:
化学与环境工程学院
摘要:
以2,5-二取代-1,3,4-噁二唑为中心核,酯基(COO)为桥键,烷基(n=5~9)为末端基团,在单侧苯环侧位上引入氟原子,设计合成了两个系列新型不对称弯曲形液晶化合物9a-9e和10a-10e;并通过IR,^1HNMR,^13CNMR,^19FNMR和MS对其结构进行鉴定,经差热扫描仪(DSC)和偏光显微镜(POM)测定其液晶相态.结果表明:所有目标化合物的分子结构正确,都呈现向列相态,向列相态温度范围最宽达78℃;侧位单氟苯环结构化合物9a-9e的向列相态温度范围没有二氟苯环结构10a-10e的宽,并且化合物9a-9e都呈现奇偶效应.
摘要(英文):
Two novel series of bent-core liquid crystals (9a similar to 9e and 10a similar to 10e) were prepared with a central bent core based on 2,5-disubstitueted-1,3,4-oxadiazole, ester group bridge (coo), alkyl tails with different carbon numbers (n=5 similar to 9), and one side wing substituted by fluorine atom. The structures of the target compounds were confirmed by IR, H-1 NMR, C-13 NMR, MS, and their transition temperatures and phase textures were investigated by using differential scanning calorimetric (DSC) and polarizing optical microscopy (POM). The result suggested that all target compound...

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