In this study, the effect of biochar supported nano-zero valent iron (nZVI/BC) on anaerobic digestion of sulfate wastewater including methane yield, total volatile fatty acids, COD balance, sulfur balance, variation of iron (Fe2+) and microbial community structure was investigated by a batch-scale experiment. The results showed that nZVI/BC could effectively maintain the stability of anaerobic digestion even at a high sulfate concentration. At SO42−/COD = 0.1 with 2 g nZVI/BC, the maximum methane yield (Bmax) and maximum methane production rat...