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Reverse micelles in carbon dioxide with ionic-liquid domains

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成果类型:
期刊论文
作者:
Liu, Jiehua;Cheng, Siqing;Zhang, Jianling;Feng, Xiaoying;Fu, Xiangang;...
通讯作者:
Han, Buxing
作者机构:
[Han, Buxing] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China.
Wuhan Polytech Univ, Dept Chem & Environm Engn, Wuhan 430023, Peoples R China.
通讯机构:
[Han, Buxing] C
Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China.
语种:
英文
关键词:
carbon dioxide;ionic liquids;micelles;nanoparticles;supercritical fluids
期刊:
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
ISSN:
1433-7851
年:
2007
卷:
46
期:
18
页码:
3313-3315
机构署名:
本校为其他机构
院系归属:
化学与环境工程学院
摘要:
The fluorinated surfactant N-ethyl perfluorooctylsulfonamide can form reverse micelles with an ionic liquid as the inner component in supercritical CO2. These reverse micelles can solubilize salts and gold nanoparticles can be formed with HAuCl4 (see TEM image). The micellar systems may combine some of the advantages of supercritical CO2 and ionic liquids as solvents with benefits for potential applications. (Chemical Equation Pre...

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