期刊论文

Zhang, Z.

中文

功能材料

1001-9731

2016

47

B06

153-158

10.3969/j.issn.1001-9731.2016.Supplement(1).027

11074054:国家自然科学基金 11374067:国家自然科学基金

本校为第一且通讯机构

采用Adler-Longo法,设计合成了两种系列共8种具有对称结构的中位四取代酯类卟啉化合物,通过~1H NMR,~（13）C NMR,IR对其分子结构进行了表征,通过紫外-可见光谱法（UV）、荧光光谱法（PL）和循环伏安法（CV）对这些化合物的光电性能进行了研究;结果表明,所合成的中位四取代酯类卟啉化合物结构正确,并均具有较高的荧光量子效率、较低的轨道能隙,是一类较好的光致电材料,在有机半导体材料、有机太阳能电池等方面具有潜在的应用前景。

Using the Adler-Longo method, the two series of the 8 kinds of a median tetra-substituted ester porphyrin compounds which has the symmetrical structure have been designed and synthesized in this paper, and their structure was characterized by 1H NMR, 13C NMR, IR. Their optoelectronic properties were studied by UV-Vis absoption spectra and Fluorescence emission spectra, and its orbital energy level was studied by the cyclic voltammetry. Results indicate that the synthesis of the median tetra-substituted ester porphyrin compounds have a high quan...