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Selective hydrothermal degradation of cellulose to formic acid in alkaline solutions

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成果类型:
期刊论文
作者:
Wang, Guozhen;Meng, Yan;Zhou, Jinping*;Zhang, Lina*
通讯作者:
Zhou, Jinping;Zhang, Lina
作者机构:
[Zhou, Jinping; Wang, Guozhen; Meng, Yan; Zhang, Lina; Zhou, JP] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China.
[Zhang, Lina] Guangxi Univ, Sch Chem & Chem Engn, Nanning 530004, Peoples R China.
[Wang, Guozhen] Wuhan Polytech Univ, Coll Food Sci & Engn, Key Lab Deep Proc Major Grain & Oil, Minist Educ,Hubei Key Lab Proc & Transformat Agr, Wuhan 430023, Hubei, Peoples R China.
通讯机构:
[Zhou, JP; Zhang, LN] W
Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China.
语种:
英文
关键词:
Cellulose degradation;NaOH/ZnO aqueous solution;Selectivity of oxidative reaction;Organic acids
期刊:
Cellulose
ISSN:
0969-0239
年:
2018
卷:
25
期:
10
页码:
5659-5668
基金类别:
Major Program of National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21334005]; Major International Joint Research ProjectNational Natural Science Foundation of China (NSFC) [21620102004]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [51473128]
机构署名:
本校为其他机构
院系归属:
食品科学与工程学院
摘要:
Abstract: Herein, one-step conversion of cellulose dissolved in 1.75molL−1 NaOH/0.074molL−1 ZnO aqueous solution to organic acids was realized through a hydrothermal degradation without heterogeneous catalyst. The effects of solvent, the concentrations of NaOH and ZnO, O2 pressure, temperature and the reaction time on the yield of organic acids were investigated and discussed. The components of the degraded products were characterized with total organic carbon and high performance liquid chromatography. The results indicated that cellulose wa...

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