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Preparation and evaluation of n-octadecylphosphonic acid-modified magnesia–zirconia stationary phases for reversed-phase liquid chromatography

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成果类型:
期刊论文
作者:
He, HB;Feng, YQ*;Qu-Li;Da, SL;Hu, ZX
通讯作者:
Feng, YQ
作者机构:
[Feng, YQ] Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China.
Wuhan Polytech Univ, Dept Food Sci, Wuhan 430072, Peoples R China.
通讯机构:
[Feng, YQ] W
Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China.
语种:
英文
关键词:
Alkaloids;Basic compounds;Magnesia-zirconia;Octadecylphosphonic acid-modified;Reversed-phase liquid chromatography;Stationary phases
期刊:
Analytica Chimica Acta
ISSN:
0003-2670
年:
2005
卷:
542
期:
2
页码:
268-279
基金类别:
This work was financially supported in part by the National Natural Science Foundation of China (Grant No. 20475040) and the Excellent Young Teachers Program of MOE, China.
机构署名:
本校为其他机构
院系归属:
食品科学与工程学院
摘要:
Three n-octadecylphosphonic acid-modified magnesia-zirconia reversed stationary phases (C18PZM) are prepared via the strong Lewis base interactions between organophosphonate and magnesia-zirconia composite. And two of them are end-capped by using trimethylchlorosilane as end-capping agent in different procedures. Stability studies at extreme high pH conditions (pH 9-12) show that both the non-endcapped and endcapped columns are quite stable at pH 12 mobile phase. The reversed-phase liquid chromatographic behavior of three C18PZM stationary phas...

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