Functionalized phenoxy-imine catalyst for synthesizing highly crystalline nascent UHMWPEs: 2: The non-isothermal crystallization kinetics towards the nascent less entangled UHMWPEs
The research is supported by the Research Funding of Wuhan Institute of Technology ( 000017/20QD04 ), the Research Funding of Wuhan Polytechnic University ( 118/53210052143 ). We are also specially grateful to Dr. Chen Xiangjian’ unselfish help for his expertise on DSC instrumentation.
机构署名：
本校为第一机构
院系归属：
化学与环境工程学院
摘要：
The morphologies and molecular weight characteristics of nascent UHMWPEs were reported in our previous work. In order to understand the effect of entanglement state on non-isothermal crystallization behaviors and kinetics of the nascent UHMWPEs, a comprehensive thermal analysis was implemented. The nascent UHMWPEs were confirmed as nascent less entangled UHMWPEs from annealing-crystallization-melting cycles. Jeziorny and Mo methods were applied to describe the non-isothermal crystallization kinetics of the UHMWPEs. The effects of entanglement d...
