期刊论文

Bara, Jason E.;Verevkin, Sergey P.

英文

ACS SUSTAINABLE CHEMISTRY & ENGINEERING

2168-0485

2017

5

1

911-921

10.1021/acssuschemeng.6b02231

D.A.W. and J.E.B. acknowledge partial support from the National Science Foundation (REU supplement to CBET-1139597). V.N.E. acknowledges partial support from the Russian Government Program of Competitive Growth of Kazan Federal University and Russian Foundation for Basic Research (15-03-07475). M.W. acknowledges partial support from the Hubei Provincial Department of Education and Wuhan Polytechnic University. J.E.B. thanks Dr. Kenneth A. Belmore from the University of Alabama Department of Chemistry for acquisition of 1H and 13C NMR spectra. J.E.B. also thanks Dr. Steven Kelley from University of Alabama Department of Chemistry for performing the Karl Fischer titrations.

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1,2,3-Trimethoxypropane (1,2,3-TMP) is the trimethyl ether of propane-1,2,3-triol, better known as glycerol, which can be derived from triglycerides originating from either plant or animal sources. Despite its simple structure and the ubiquity of its glycerol precursor, successful synthesis of 1,2,3-TMP was only recently reported in the literature, with studies suggesting it may be a “green” and nontoxic alternative to solvents such as diglyme, a constitutional isomer. However, no thermophysical properties of 1,2,3-TMP have yet been reported....