This paper describes the effect of four types of amine (ethylenediamine, diethylenetriamine, triethylenetetramine, tetraethylenepentamine) as polar additives on the critical micellar concentrations (CMCs) of ionic surfactants, [cetyltrimethylammonium bromide (CTAB) and sodium dodecyl sulfate (SDS)] in buffered solutions (I=0.1 M KN03, 0.01 M Tris-TrisH+) at pH 7.00 ±0.01 by electrical conductivity. It was found that the CMCs of these surfactants all decreased with increasing amine concentrations and the extent of effect followed the sequence: tetraethylenepentamine >triethylenetetram...