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Effects of amine additives on critical micelle concentration of ionic surfactants

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成果类型:
期刊论文
作者:
Jiang, BY;Du, J;Cheng, SQ;Wang, Q;Zeng, XC*
通讯作者:
Zeng, XC
作者机构:
[Zeng, XC] Sichuan Univ, Fac Chem, Chengdu 610064, Peoples R China.
Wuhan Polytech Coll, Dept Biol & Chem Engn, Wuhan, Hubei, Peoples R China.
通讯机构:
[Zeng, XC] S
Sichuan Univ, Fac Chem, Chengdu 610064, Peoples R China.
语种:
英文
关键词:
Amine additives;Critical micelle concentration;Hydrogen bond interaction;Ionic surfactants
期刊:
Journal of Dispersion Science and Technology
ISSN:
0193-2691
年:
2003
卷:
24
期:
6
页码:
755-760
机构署名:
本校为其他机构
院系归属:
生命科学与技术学院
摘要:
This paper describes the effect of four types of amine (ethylenediamine, diethylenetriamine, triethylenetetramine, tetraethylenepentamine) as polar additives on the critical micellar concentrations (CMCs) of ionic surfactants, [cetyltrimethylammonium bromide (CTAB) and sodium dodecyl sulfate (SDS)] in buffered solutions (I=0.1 M KN03, 0.01 M Tris-TrisH+) at pH 7.00 ±0.01 by electrical conductivity. It was found that the CMCs of these surfactants all decreased with increasing amine concentrations and the extent of effect followed the sequence: tetraethylenepentamine >triethylenetetram...

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