Microwave-Assisted Solvent-Free Synthesis of Zeolitic Imidazolate Framework-67

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成果类型：

期刊论文

作者：

Zhang, Heng;Zhong, Jing*;Zhou, Guoxiang;Wu, Junliang;Yang, Zhenyu;...

通讯作者：

Zhong, Jing;Shi, Xianming

作者机构：

[Zhong, Jing; Zhang, Heng] Harbin Inst Technol, Minist Educ, Key Lab Struct Dynam Behav & Control, Harbin 150090, Heilongjiang, Peoples R China.

[Zhong, Jing; Zhang, Heng] Harbin Inst Technol, Sch Civil Engn, Harbin 150090, Peoples R China.

[Zhong, Jing; Wu, Junliang; Zhang, Heng; Zhou, Guoxiang] Wuhan Polytech Univ, Sch Civil Engn & Architecture, Wuhan 430023, Peoples R China.

[Yang, Zhenyu] Nanchang Univ, Dept Chem, Nanchang 330031, Peoples R China.

[Shi, Xianming] Washington State Univ, Dept Civil & Environm Engn, POB 642910, Pullman, WA 99164 USA.

通讯机构：

[Zhong, Jing] H

[Zhong, Jing; Shi, Xianming] W

Harbin Inst Technol, Minist Educ, Key Lab Struct Dynam Behav & Control, Harbin 150090, Heilongjiang, Peoples R China.

Harbin Inst Technol, Sch Civil Engn, Harbin 150090, Peoples R China.

Wuhan Polytech Univ, Sch Civil Engn & Architecture, Wuhan 430023, Peoples R China.

语种：

英文

期刊：

Journal of Nanomaterials

ISSN：

1687-4110

年：

2016

卷：

2016

页码：

1-9

DOI：

10.1155/2016/9648386

基金类别：

National Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [51402074, 21263016]; Jiangsu Postdoctoral Science FoundationChina Postdoctoral Science Foundation [1402129C]; Six Talent Peaks Program of Jiangsu Province [2013-ZBZZ-032]; Lianyungang Scientific Plan-Joint Project of Industry-Academia-Research [CXY1405]

机构署名：

本校为通讯机构

院系归属：

土木工程与建筑学院

摘要：

A microporous metal-organic framework (MOF), cobalt-based zeolitic imidazolate framework-67 (ZIF-67), was synthesized by the combination of solvent-free hand-mill and microwave irradiation, without any organic solvent and within 30 minutes. The hand-milling process can mix the reactants well by the virtue of high moisture/water absorption capacity of reactants. In addition, the outstanding electromagnetic wave absorption capability of cobalt leads to efficient conversion to MOF structures before carbonization. The obtained ZIF-67 posse...

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