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Capacitive Nanosized Spinel alpha-LiFe5O8 as High Performance Cathodes for Lithium-ion Batteries

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成果类型:
期刊论文
作者:
Zhou, Wei*;Wang, Yourong;Zhang, Liping;Song, Guangsen;Cheng, Siqing
通讯作者:
Zhou, Wei
作者机构:
[Wang, Yourong; Cheng, Siqing; Song, Guangsen; Zhou, Wei; Zhang, Liping] Wuhan Polytech Univ, ICNEM, Sch Chem & Environm Engn, Wuhan 430023, Hubei, Peoples R China.
通讯机构:
[Zhou, Wei] W
Wuhan Polytech Univ, ICNEM, Sch Chem & Environm Engn, Wuhan 430023, Hubei, Peoples R China.
语种:
英文
关键词:
alpha-LiFe5O8;Cathodes;Capacitive;Lithium-ion batteries
期刊:
International Journal of Electrochemical Science
ISSN:
1452-3981
年:
2015
卷:
10
期:
6
页码:
5061-5068
基金类别:
Education Foundation of Hubei Province [T200908]; Project of Chinese Ministry of EducationMinistry of Education, China [208088]
机构署名:
本校为第一且通讯机构
院系归属:
化学与环境工程学院
摘要:
The nanosized spinel alpha-LiFe5O8 with a grain size of about 10 nm was fabricated by a facile solid state method via the assistance of oxalic acid. The as-prepared alpha-LiFe5O8 electrode for lithium ion battery delivers a high reversible initial specific capacity of 257.1 mA h g(-1) at 28 mA g(-1) and remaining at 130 mAh g(-1) at as high as 2820 mA g(-1) even after 100 cycles, as well as excellent rate capability and improved cycling stability, which has not reported before for lithium ferrite oxides. This might be attributed to the characteristic pseudocapacitive behavior of lithium storag...

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