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Iron-catalyzed cross-coupling reaction of alkyl halides with biphenyl grignard reagent

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成果类型:
期刊论文
作者:
Dai, Z. Q.;Liu, K. Q.;Zhang, Z. Y.*;Wei, B. M.;Guan, J. T.
通讯作者:
Zhang, Z. Y.
作者机构:
[Liu, K. Q.; Wei, B. M.; Guan, J. T.; Zhang, Z. Y.; Dai, Z. Q.] Wuhan Polytech Univ, Sch Chem & Environm Engn, Wuhan 430023, Peoples R China.
通讯机构:
[Zhang, Z. Y.] W
Wuhan Polytech Univ, Sch Chem & Environm Engn, Wuhan 430023, Peoples R China.
语种:
英文
关键词:
Cross-coupling;Grignard reagent
期刊:
Asian Journal of Chemistry
ISSN:
0970-7077
年:
2013
卷:
25
期:
11
页码:
6303-6305
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [11074054]; Foundation of Hubei Educational Commission [B20111702]; Foundation of Hubei Educational Commission for Distinguished Young Scholars [Q20111740]
机构署名:
本校为第一且通讯机构
院系归属:
化学与环境工程学院
摘要:
In the presence of a catalytic amount of iron salts and N,N,N',N'-tetramethylethylene diamine as additive, alkyl bromide reacted with biphenyl magnesium bromide to obtain the cross-coupling product in good yields. The suitable amount of catalyst and the additive are 5 % mol (based on alkyl bromide), 1.3 equiv(based on alkyl bromide), respectively. Under the optimal conditions, the yie...

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