期刊论文

A study on the synthesis of isopropylidene malonate derivatives

中文

武汉工程大学学报

1674-2869

2002

24

3

11-13

10.3969/j.issn.1674-2869.2002.03.003

本校为第一机构

以丙二酸亚异丙酯为原料经缩合,还原合成了5-烃基丙二酸亚异丙酯.5-烃基丙二酸亚异丙酯在相转移催化条件下与过氧化苯甲酰反应,以高产率合成了5-烃基5-苯甲酰氧基丙二酸亚异丙酯.这些新化合物的结构经IR,1HNMR和元素分析确证.

Under phasetranfer catalysis isopropylidene 5alkyl5o(benzoyloxy)malonates are readily prepared in high yield by the reaction of benzoyl peroxide with isopylidene 5alkyl malonates which are synthesized through condensation and reduction reaction of isopropylidene malonate.The structures of the new compounds were character...