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Synthesis of 5-hydroxymethyl furfural from cellulose via a two-step process in polar aprotic solvent

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成果类型:
期刊论文
作者:
Fan, Guozhi*;Wang, Yuexin;Hu, Zongxiao;Yan, Juntao;Li, Jianfen;...
通讯作者:
Fan, Guozhi
作者机构:
[Hu, Zongxiao; Wang, Yuexin; Li, Jianfen; Song, Guangsen; Yan, Juntao; Fan, Guozhi] Wuhan Polytech Univ, Sch Chem & Environm Engn, Wuhan 430023, Hubei, Peoples R China.
通讯机构:
[Fan, Guozhi] W
Wuhan Polytech Univ, Sch Chem & Environm Engn, Wuhan 430023, Hubei, Peoples R China.
语种:
英文
关键词:
5-Hydroxymethyl furfural;Cellulose;Glucose;Phosphotungstic acid;Two-step process
期刊:
Carbohydrate Polymers
ISSN:
0144-8617
年:
2018
卷:
200
页码:
529-535
基金类别:
This work was supported by Hubei Important Project of Technological Innovation ( 2018ABA094 ).
机构署名:
本校为第一且通讯机构
院系归属:
化学与环境工程学院
摘要:
The synthesis of 5-hydroxymethyl furfural (HMF) from cellulose via a two-step process was investigated. To optimize reaction conditions, the separate conversion of cellulose and glucose was first performed in tetrahydrofuran (THF) and N, N-dimethylformamide (DMF) via a one-step process using hosphotungstic acid (PHA) as catalyst. The direct conversion of cellulose to HMF was then performed via the two-step process. The first step and the second step were carried out in THF and the mixture solvent composed of THF/DMF, respectively. Cellulose was...

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