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Synthesis, crystal structure, phosphate hydrolysis activity and antibacterial activity of macrocyclic dinuclear Zn(II) complex with benzyl pendant-arms

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成果类型:
期刊论文
作者:
Kou, Huizhi;Wang, Yang;Ding, Peipei;Cheng, Xianzhong;Zhou, Guoqing*
通讯作者:
Zhou, Guoqing
作者机构:
[Wang, Yang; Cheng, Xianzhong; Ding, Peipei; Zhou, Guoqing; Kou, Huizhi] Wuhan Polytech Univ, Sch Chem & Environm Engn, Wuhan 430023, Peoples R China.
通讯机构:
[Zhou, Guoqing] W
Wuhan Polytech Univ, Sch Chem & Environm Engn, Wuhan 430023, Peoples R China.
语种:
英文
关键词:
Macrocyclic dinuclear;Crystal structure;Phosphate ester hydrolysis;Weak intermolecular interactions;Antibacterial activity
期刊:
Journal of Molecular Structure
ISSN:
0022-2860
年:
2020
卷:
1216
页码:
128299
基金类别:
Important Project of technological Innovation of Hubei Province#&#&#2018ABA094 National Key R&D Program of China#&#&#2016YFD0501307 Hubei Key Laboratory of Animal Nutrition and Feed Science#&#&#202007
机构署名:
本校为第一且通讯机构
院系归属:
化学与环境工程学院
摘要:
A new macrocyclic dinuclear Zn(II) complex is synthesized by the cyclocondensation between 3,3 '(ethane-1,2-diylbis (benzylazanediyl))bis(methylene) bis (2-hydroxy-5-methyl-benzaldehyde) and 1,3-diaminopropane and the subsequent with zinc salts. The as-prepared complex is characterized by elemental analysis, FT-IR, ES-MS and single crystal X-ray diffraction. The complex consists of one independent molecular unit of [Zn-2(mu-OAC)L](+) ClO4- and two water molecules with one on a symmetry element. Four of these units collectively form two pairs of dinuclear complex units of [Zn-2(mu-OAc)L](+) wit...

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