Coal, due to its heterogenous nature and complex structure; physical, chemical and petrographic, introduces two-fold complications during its combustion in power generation. Organic and inorganic constituents in various petrographic states alter chemically and physically. The products of coal combustion; unburned carbon, deposits, oxides of metals and non-metals, metal and non-metal complexes, need to be identified qualitatively and quantitatively to increase the coal combustion efficien...