A 1 at% carbon non-equiatomic doped Co19Cr5Fe38Ni19Mn19 high-entropy alloy was synthesized by vacuum arc-melting in a high-purity argon atmosphere, followed by homogenization, cold rolling, and annealing under various conditions. The evolutions of microstructure and mechanical properties during annealing were systematically studied and compared with the carbon free alloy. Results showed that nano-sized fibrous deformation grains were formed in the 90% cold rolled alloys, resulting in high strength but low plasticity. Recovery sub-structures and recrystallized grains gradually formed with incre...