Through general property tests, rheological measurements, SEM observations and weight changes after immersion, electrochemical methods and water vapor transmission tests, a waterborne zinc-rich coating from sodium silicate solution catalyzed by ammonium acetate was characterized. Results showed that the formula catalyzed by ammonium acetate overcame the poor water resistance of other non-catalyzed coatings, while binding the zinc powder in the film. The zinc-rich film had the basic features required for a zinc-rich primer to be useful and was electrochemically cathodically protective during te...