Recent innovations have created various two-dimensional membranes to break the Li+/Mg2+ selectivity limit of traditional separation membranes. However, the simultaneous achievement of ultrafast transport and high selectivity is still below the theoretical prediction. Herein, for overcoming these shortcomings, the twodimensional montmorillonite membrane (2D MMT membrane) consisting of sulfonated polyvinyl alcohol (SPVA), ethylene glycol (EG), and polyacrylamide (PAM) is proposed based on the design of porous 2D nano channels. It is found that the SPVA can effectively improve the membrane stabil...