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Novel bimetallic MIL-53(Fe/Mn) as dual cocatalysts promote charge separation efficiency of CdS for photocatalytic reduction of CO2

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成果类型:
期刊论文
作者:
Xuan, Ruina;Chen, Jiwen;Dou, Yixin;Jiang, Zhuo;Li, Xiaofang;...
通讯作者:
Ding, D
作者机构:
[Dou, Yixin; Ding, Deng; Wang, Chunlei; Yan, Juntao; Li, Xiaofang; Chen, Jiwen; Xuan, Ruina] Wuhan Polytech Univ, Coll Chem & Environm Engn, Wuhan 430023, Peoples R China.
[Jiang, Zhuo] Wuhan Univ, Sch Elect Engn & Automat, Wuhan 430072, Peoples R China.
[Sun, Linbing] Nanjing Tech Univ, Coll Chem Engn, Nanjing 211816, Peoples R China.
通讯机构:
[Ding, D ] W
Wuhan Polytech Univ, Coll Chem & Environm Engn, Wuhan 430023, Peoples R China.
语种:
英文
关键词:
Bimetallic MOFs;Dual cocatalysts;CO 2 reduction;Charge separation
期刊:
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
ISSN:
2213-2929
年:
2025
卷:
13
期:
1
页码:
115293
基金类别:
WHPU Foundation Inno-vation and Entrepreneurship Training Project for College Students [2024J03, XQ2024004]; [202410496023]
机构署名:
本校为第一且通讯机构
院系归属:
化学与环境工程学院
摘要:
Dual-co-catalyst-modified photocatalysts enhance charge separation efficiency, but the traditional dual co-catalyst is still difficult to get a high separation efficiency due to size and aggregation. Herein, we report bimetallic MIL-53(Fe/Mn) as dual co-catalysts with separate electron and hole mediators. CdS NPs were in-situ grown into MIL-53(Fe/Mn) at varying ratios. 20 %CdS/MIL-53(Fe/Mn) composites shown optimum photocatalytic CO 2 reduction activity. The XPS results shown the strong interaction between CdS and MIL-53(Fe/Mn). The EPR measur...

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