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Aggregated and ionic cross-linked anion exchange membrane with enhanced hydroxide conductivity and stability

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成果类型:
期刊论文
作者:
Han, Juanjuan*;Lin, Bencai;Peng, Hanqing;Zhu, Yuchan;Ren, Zhandong*;...
通讯作者:
Han, Juanjuan;Ren, Zhandong
作者机构:
[Zhu, Yuchan; Han, Juanjuan; Ren, Zhandong] Wuhan Polytech Univ, Sch Chem & Environm Engn, Wuhan 430023, Peoples R China.
[Lin, Bencai] Changzhou Univ, Jiangsu Collaborat Innovat Ctr Photovolat Sci & E, Sch Mat Sci & Engn, Changzhou 213164, Peoples R China.
[Peng, Hanqing; Zhuang, Lin; Xiao, Li] Wuhan Univ, Coll Chem & Mol Sci, Hubei Key Lab Electrochem Power Sources, Wuhan 430072, Peoples R China.
通讯机构:
[Han, JJ; Ren, ZD] W
Wuhan Polytech Univ, Sch Chem & Environm Engn, Wuhan 430023, Peoples R China.
语种:
英文
关键词:
Alkalinity;Ammonia;Chemical stability;Crosslinking;Economic and social effects;Ion exchange;Ion exchange membranes;Ionic strength;Microphase separation;Sodium hydroxide;Tensile strength;Tensile testing;Anion exchange membrane;Cross-linked networks;Hydroxide conductivities;Ionic cross linking;Micromorphologies;Peak power densities;Stability tests;Strength and elongations;Alkaline fuel cells
期刊:
Journal of Power Sources
ISSN:
0378-7753
年:
2020
卷:
459
期:
May 31
页码:
227838
基金类别:
This work was financially supported by the National Natural Science Foundation of China ( 21802038 , 3110370 , 51973022 ), the Natural Science Foundation of Hubei Province ( 2018CFB329 ), Jiangsu Key State Laboratory Cultivation base for Photovolatic Engineering Science ( SKLPST201704 ).
机构署名:
本校为第一且通讯机构
院系归属:
化学与环境工程学院
摘要:
In order to achieve a better trade-off among ionic conductivity, mechanical strength and chemical stability, a series of novel aggregated and ionic cross-linked anion exchange membranes (AEMs) are recommended, namely, acS(6)QAPSF, acS(8)QAPSF and acS(10)QAPSF. Cross-linked network shoulders the responsibility to toughen the acS(x)QAPSF. Appropriate micro-morphology is responsible for facilitating the conduction of OH- and improving the alkaline stability of the acS(x)QAPSF. Compared with the original QAPSF, acS(x)QAPSF membranes exhibit much better properties. Specifically, for acS(8)QAPSF, a ...

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