The coagulant comparison reaction experiment of polyaluminium chloride and polymeric aluminum ferric sulfate was studied in the treatment of chemical fiber wastewater as flocculants. Application conditions of advanced polyaluminium was selected through comparative analysis. The optimal reaction conditions of polyaluminium were determined: the pH of acidolysis was controlled at 2.20 and before flocculation the pH of wastewater was adjusted to 5, the optimal dose of polyaluminium was 3%o, the cationic PAM was selected as coagulant aid and its op...