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Promoting CuO/Cu(OH)2 for electrocatalytic reduction of CO2 to HCOOH: The study on pyridine-modified surface active sites

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成果类型:
期刊论文
作者:
Zhou, Yintong;Ren, Xiaohui;Wang, Xusheng;Mao, Jiayao;Zhang, Haoran;...
通讯作者:
Chen, RS;Ren, XH
作者机构:
[Wang, Jiaxing; Zhou, Yintong; Ma, Feng; Zhang, Haoran; Chen, Rongsheng; Mao, Jiayao; Yang, Yan] Wuhan Univ Sci & Technol, Inst Adv Mat & Nanotechnol, Sch Chem & Chem Engn, State Key Lab Refractories & Met, Wuhan 430081, Peoples R China.
[Ren, Xiaohui; Ni, Hongwei] Wuhan Univ Sci & Technol, Minist Educ, State Key Lab Refractories & Met & Resources Utili, Key Lab Ferous Metalurgy, Wuhan 430081, Peoples R China.
[Ren, Xiaohui; Ni, Hongwei] Wuhan Univ Sci & Technol, Fac Mat, Hubei Prov Key Lab New Proc Ironmaking & Steel mak, Wuhan 430081, Peoples R China.
[Wang, Xusheng] Zhejiang Sci Tech Univ, Sch Mat Sci & Engn, Hangzhou 310018, Peoples R China.
[Liu, Huating] Wuhan Polytech Univ, Sch Elect & Elect Engn, Wuhan 430023, Peoples R China.
通讯机构:
[Chen, RS ; Ren, XH ] W
Wuhan Univ Sci & Technol, Inst Adv Mat & Nanotechnol, Sch Chem & Chem Engn, State Key Lab Refractories & Met, Wuhan 430081, Peoples R China.
Wuhan Univ Sci & Technol, Minist Educ, State Key Lab Refractories & Met & Resources Utili, Key Lab Ferous Metalurgy, Wuhan 430081, Peoples R China.
Wuhan Univ Sci & Technol, Fac Mat, Hubei Prov Key Lab New Proc Ironmaking & Steel mak, Wuhan 430081, Peoples R China.
语种:
英文
关键词:
CO2RR;Copper-based catalyst;Pyridine;Modification;Surface active sites
期刊:
Molecular Catalysis
ISSN:
2468-8231
年:
2024
卷:
556
页码:
113929
基金类别:
National Natural Science Foundation of China [U21A20317, 22109121, 22309141, U23A20606]; National Key R & D Program of China [2020YFC1909702]; Key Laboratory of Hubei Province for Coal Conversion and New Carbon Materials [WKDM202204]; National key research and develop- ment program of China [2022YFB3207200]; High -Performance Computing Center of Wuhan University of Science and Technology
机构署名:
本校为其他机构
院系归属:
电气与电子工程学院
摘要:
Copper -based catalysts have been extensively investigated for electrocatalytic reduction of CO2 owing to their unique capabilities. To our notice, organic molecules can be employed as molecular modifiers to tailor the CO2 reduction selectivity of Cu -based catalysts. Herein, three kinds of molecular modifiers, pyridine, triethylamine, and potassium hydroxide have been utilized for fabricating Cu -based electrocatalysts. Experimental investigations reveal that pyridine as molecular modifiers have the ability to alter the surface active sites of the Cubased catalysts. The modification can facil...

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