Polysilicon sludge (PSS), due to its high organic impurity content, poses significant challenges in solidification using traditional cementitious materials, failing to meet engineering standards. As such, alternative solidification methods are urgently needed to enhance PSS resource utilization. This study explores the use of phosphogypsum (PG) to improve the alkali activation process in the solidification of PSS with slag. Given that calcium sulfate in PG promotes alkali activation, this research investigates the synergistic effects of PG, PSS, and slag as precursors in developing an eco-frie...