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New insight into the changes in metal-phosphonate complexes from the addition of CaCO3 to enhance ferric flocculation for efficient phosphonate removal

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成果类型:
期刊论文
作者:
Zeng, Chaocheng;Hu, Huimin;Wang, Chao;Shi, Qing;Zhang, Qiwu;...
通讯作者:
Hu, H.;Zhang, Q.
作者机构:
[Wang, Chao; Chen, Mengfei; Wang, Qian; Zeng, Chaocheng; Zhang, Qiwu; Shi, Qing; Hu, Huimin] Wuhan Univ Technol, Sch Resources & Environm Engn, Luoshi Rd 122, Wuhan 430070, Hubei, Peoples R China.
[Zhang, Tingting] Wuhan Polytech Univ, Sch Chem & Environm Engn, Wuhan 430023, Hubei, Peoples R China.
通讯机构:
[Huimin Hu; Qiwu Zhang] S
School of Resources and Environmental Engineering, Wuhan University of Technology, Luoshi Road 122, Wuhan, Hubei, 430070, China
语种:
英文
关键词:
CaCO3;Ferric flocculation;Phosphonate removal;Ternary bridging complexes
期刊:
Chemosphere
ISSN:
0045-6535
年:
2023
卷:
311
页码:
137078
基金类别:
Author contributions statement Chaocheng Zeng: Investigation, Formal analysis, Data curation, Writing, Original draft preparation; Huimin Hu: Methodology, Validation, Project administration, Visualization; Chao Wang: Investigation, acquisition; Qing Shi: Investigation, Data curation; Qiwu Zhang: Conceptualization, Project administration, Resources, Supervision, Writing - Review & Editing; Mengfei Chen: Supervision; Qian Wang: Supervision; Tingting Zhang: Supervision, Visualization.
机构署名:
本校为其他机构
院系归属:
化学与环境工程学院
摘要:
Due to the stable chelating effect of organic phosphonates in wastewater, phosphonates with increasing emission are difficult to be removed effectively by traditional ferric salt flocculation, which has posed tough challenges for reducing total phosphorus pollution in recent years. In this work, calcium carbonate (CaCO3) was introduced to work together with the widely investigated flocculant of ferric chloride (FeCl3) to realize an efficient removal of nitrilotrismethylenephosphonic acid (NTMP) at much lower dosage of FeCl3. With an aid of syne...

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