Scientific Research Projects from Hubei Provincial Department of Education [D20141704]
机构署名：
本校为第一且通讯机构
院系归属：
化学与环境工程学院
摘要：
Cu(acac)2/n-Bu4NBr/Fe3O4@MCM-41 was prepared by supporting Cu(acac)2as well as n-Bu4NBr on complex support of Fe3O4@MCM-41 and developed as binary supported catalyst for the synthesis of styrene carbonate (SC) via the coupling reaction of styrene oxide (SO) with carbon dioxide (CO2). The activity of the supported catalyst was investigated by supporting Cu(acac)2and n-Bu4NBr alone or together, varying molar ratio of materials and reaction conditions including CO2pressure, reaction temperature as well as time. Cu(acac)2/n-Bu4NBr/Fe3O4@MCM-41 displayed higher catalytic activity than that of singl...
