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Coupling reaction of carbon dioxide with styrene oxide over Cu(acac)2 and n-Bu4NBr supported on Fe3O4@MCM-41

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成果类型:
期刊论文
作者:
Fan, Guozhi*;Wang, Yuexin;Yan, Juntao;Song, Guangsen;Li, Jianfen*
通讯作者:
Fan, Guozhi;Li, Jianfen
作者机构:
[Wang, Yuexin; Li, Jianfen; Song, Guangsen; Yan, Juntao; Fan, Guozhi; Li, J] Wuhan Polytech Univ, Sch Chem & Environm Engn, Wuhan 430023, Peoples R China.
通讯机构:
[Fan, GZ; Li, J] W
Wuhan Polytech Univ, Sch Chem & Environm Engn, Wuhan 430023, Peoples R China.
语种:
英文
关键词:
Bins;Carbon dioxide;Catalyst activity;Catalysts;Chemical reactions;Copper compounds;Iron compounds;Styrene;Catalytic performance;Catalytic system;Coupling reaction;Optimized conditions;Reaction conditions;Reaction temperature;Styrene carbonates;Styrene oxide;Catalyst supports
期刊:
Journal of CO2 Utilization
ISSN:
2212-9820
年:
2017
卷:
18
页码:
370-377
基金类别:
Scientific Research Projects from Hubei Provincial Department of Education#&#&#D20141704
机构署名:
本校为第一且通讯机构
院系归属:
化学与环境工程学院
摘要:
Cu(acac)2/n-Bu4NBr/Fe3O4@MCM-41 was prepared by supporting Cu(acac)2 as well as n-Bu4NBr on complex support of Fe3O4@MCM-41 and developed as binary supported catalyst for the synthesis of styrene carbonate (SC) via the coupling reaction of styrene oxide (SO) with carbon dioxide (CO2). The activity of the supported catalyst was investigated by supporting Cu(acac)2 and n-Bu4NBr alone or together, varying molar ratio of materials and reaction conditions including CO2 pressure, reaction temperature as well as time. Cu(acac)2/n-Bu4NBr/Fe3O4@MCM-41 d...

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