This study explored the effect of Cr3C2 content (0, 0.5, 1, 1.5, and 2 mol%) on the microstructure, magnetic properties and mechanical behavior of TiC-10TiN-6WC-4C-(15,30) Ni (mol%) cermets after vacuum sintering. The results show that just Ti-based carbonitride ceramic grains and Ni-based binder phase were presented in the experimental cermets, and the mean size of ceramic grains reduced with the increase of Cr3C2 content. By adding Cr3C2 into cermets, the Cr concentration in binder phase obviously raised. However, Ti concentration in binder phase decreased continuously as Cr3C2 content incre...