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Use of Carbon Nanofibers Loaded With 1-Phenyl-3-Methyl-4-Benzoyl-5-Pyrazone for Preconcentration and Separation of Trace Rare Earth Elements Prior to Their Determination by ICP-MS

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成果类型:
期刊论文
作者:
Chen, Shizhong*;Li, Jianfen;He, Yuanyuan;Lu, Dengbo
通讯作者:
Chen, Shizhong
作者机构:
[Li, Jianfen; Chen, Shizhong; He, Yuanyuan; Lu, Dengbo] Wuhan Polytech Univ, Coll Chem & Environm Engn, 68 Xuefu South Rd Changqing Garden, Wuhan 430023, Peoples R China.
通讯机构:
[Chen, Shizhong] W
Wuhan Polytech Univ, Coll Chem & Environm Engn, 68 Xuefu South Rd Changqing Garden, Wuhan 430023, Peoples R China.
语种:
英文
期刊:
ATOMIC SPECTROSCOPY
ISSN:
0195-5373
年:
2016
卷:
37
期:
3
页码:
96-101
基金类别:
Special Fund for Agroscientific Research in the Public Interest [201503135-22]
机构署名:
本校为第一且通讯机构
院系归属:
化学与环境工程学院
摘要:
In this paper, a novel method was developed for the preconcentration, separation, and determination of light (Ce), medium (Eu and Gd), and heavy (Yb) rare earth elements (REEs) by inductively coupled plasma mass spectrometry (ICP-MS), based on the adsorption of Ce3+, Eu3+, Gd3+, and Yb3+ on carbon nanofibers (CNFs) loaded with 1-phenyl-3methyl-4-benzoyl-5-pyrazone (PMBP). The REEs can be adsorbed quantitatively on CNFs-PMBP in the pH range of 5.0 to 8.0 and then eluted completely with 1.0 mol L-1 HNO3. The experimental parameters for the preconcentration and separation of REEs, such as pH, sam...

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