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Chemical fixation of carbon dioxide catalyzed by bimetallic aluminum (salen) complex

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成果类型:
期刊论文、会议论文
作者:
Duan, Zhenxiao;Fang, Tao;Wang, Min;Fan, Guozhi*
通讯作者:
Fan, Guozhi
作者机构:
[Duan, Zhenxiao; Wang, Min; Fan, Guozhi; Fang, Tao] Wuhan Polytech Univ, Sch Chem & Environm Engn, Wuhan 430023, Peoples R China.
通讯机构:
[Fan, Guozhi] W
Wuhan Polytech Univ, Sch Chem & Environm Engn, Wuhan 430023, Peoples R China.
语种:
英文
关键词:
Bimetallic aluminum(salen) complex;carbon dioxide;phenol;diphenyl carbonate
期刊:
Advanced Materials Research
ISSN:
1022-6680
年:
2012
卷:
549
页码:
406-410
会议名称:
2012 2nd International Symposium on Chemical Engineering and Material Properties (ISCEMP2012)(2012第二届化学工程与材料特性国际研讨会)
会议论文集名称:
2012 2nd International Symposium on Chemical Engineering and Material Properties (ISCEMP2012)(2012第二届化学工程与材料特性国际研讨会)论文集
会议时间:
2012-06-23
会议地点:
太原
会议主办单位:
[Duan, Zhenxiao;Fang, Tao;Wang, Min;Fan, Guozhi] Wuhan Polytech Univ, Sch Chem & Environm Engn, Wuhan 430023, Peoples R China.
会议赞助商:
计算机科学与电子技术国际学会
主编:
Li, B
出版地:
KREUZSTRASSE 10, 8635 DURNTEN-ZURICH, SWITZERLAND
出版者:
TRANS TECH PUBLICATIONS LTD
ISBN:
978-3-03785-454-9
机构署名:
本校为第一且通讯机构
院系归属:
化学与环境工程学院
摘要:
Bimetallic aluminum(salen) complexes were prepared and used as catalyst for the synthesis of DPC from CO2 and phenol in the presence of carbon tetrachloride. The bimetallic complex derived from 3,5-ditert salicylaldehyde and 1,2-cyclohexanediamine revealed more excellent activity than that obtained in the presence of other complexes and the simple Lewis acid ZnCl2. The influence of the amount of complex and the reaction conditions including the pressur...

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