Optimization of the transport behaviors of ions and electrons is the key for the property improvement of supercapacitor, which are essentially controlled by the design of hierarchical porous structure and electrical conductive backbone, from nanoscale to microscale, respectively. However, such design requirements are very difficult to be satisfied simultaneously, because the generation of porosity would result to the detrimental effects on the electrical conductivity of electrode. In this study, we propose to prepare a hierarchical porous super...