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Realizing pure white light emission by adjusting the molar ratio of Eu3+/ Tb3+in two new Ln-based metal-organic frameworks

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成果类型:
期刊论文
作者:
Zhang, Yi;Xue, Lu;Xue, Zhen-Dong;Zhu, Hao-Yu;Chen, Wei-Min;...
通讯作者:
Wang, FM;Yang, H
作者机构:
[Chen, Wei-Min; Wang, Fang-Ming; Zhang, Yi; Zhu, Hao-Yu; Wang, FM; Xue, Zhen-Dong] Jiangsu Univ Sci & Technol, Sch Environm & Chem Engn, Zhenjiang 212003, Jiangsu, Peoples R China.
[Xue, Lu; Wen, Li-Li] Cent China Normal Univ, Coll Chem, Wuhan 430079, Hubei, Peoples R China.
[Yang, H; Yang, Heng] Wuhan Polytech Univ, Coll Chem & Environm Engn, Wuhan 430023, Peoples R China.
通讯机构:
[Yang, H ] W
[Wang, FM ] J
Jiangsu Univ Sci & Technol, Sch Environm & Chem Engn, Zhenjiang 212003, Jiangsu, Peoples R China.
Wuhan Polytech Univ, Coll Chem & Environm Engn, Wuhan 430023, Peoples R China.
语种:
英文
关键词:
Metal-organic frameworks;White-light emitting;Crystal structure;Probe;Solvothermal
期刊:
JOURNAL OF MOLECULAR STRUCTURE
ISSN:
0022-2860
年:
2025
卷:
1322
基金类别:
National Natural Science Foundation of China [22171097, 21771072]; Fundamental Research Funds for the Central Universities [CCNU22QN008]; Postgraduate Research & Practice Innovation Program of Jiangsu Province [KYCX23_3836]
机构署名:
本校为通讯机构
院系归属:
化学与环境工程学院
摘要:
Two Ln-based Metal-Organic Frameworks (MOFs), Eu-BCTC and Tb-BCTC, were synthesized using the ligand [9,9 '-bicarbazole]-3,3 ',6,6 '-tetracarboxylic acid (H4BCTC) via a solvothermal method. They emit green or red light, respectively. By adjusting the molar ratio of Eu3+/Tb3+ of LMOFs, a single-phase white light emitter, Eu0.075Tb0.925-BCTC, was successfully synthesized. This compound exhibits an ideal CIE coordinate of (0.33, 0.33), internal quantum yield (IQY) at 8.37 % and a color temperature of 5623 K. Moreover, it has excellent performance in detecting Fe3+, Cr2O72- and CrO42- , with limit...

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